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Quantum Science: Understanding Wave-Particle Duality and the Photoelectric Effect

What Is Quantum Science?

Quantum Science explores phenomena on a microscopic scale, where classical mechanics fail to explain particle behavior.

Wave-Particle Duality

Dual Nature of Light

Light exhibits both wave and particle properties.

  • Wave Properties: Diffraction and interference.
  • Particle Properties: Photoelectric effect and discrete photon interactions.

The Photoelectric Effect

Key Equation

The energy of a photon is given by:

E=hfE = hfE=hf

Where:

  • EEE: Energy (JJJ).
  • h=6.63×10−34 J\cdotpsh = 6.63 \times 10^{-34} \, \text{J·s}h=6.63×10−34J\cdotps: Planck’s constant.
  • fff: Frequency (HzHzHz).

Work Function (ϕ\phiϕ)

The minimum energy required to eject an electron:

KE=hf−ϕKE = hf – \phiKE=hf−ϕ

Example: Calculate the kinetic energy of an ejected electron when light of frequency 6×1014 Hz6 \times 10^{14} \, \text{Hz}6×1014Hz hits a metal with a work function of 2.5 eV2.5 \, \text{eV}2.5eV:

  1. Convert Work Function to Joules:

ϕ=2.5⋅1.6×10−19=4.0×10−19 J\phi = 2.5 \cdot 1.6 \times 10^{-19} = 4.0 \times 10^{-19} \, \text{J}ϕ=2.5⋅1.6×10−19=4.0×10−19J

  1. Photon Energy:

E=hf=6.63×10−34⋅6×1014=3.978×10−19 JE = hf = 6.63 \times 10^{-34} \cdot 6 \times 10^{14} = 3.978 \times 10^{-19} \, \text{J}E=hf=6.63×10−34⋅6×1014=3.978×10−19J

  1. Kinetic Energy:

KE=E−ϕ=3.978×10−19−4.0×10−19=−2.2×10−21 J (electron not ejected)KE = E – \phi = 3.978 \times 10^{-19} – 4.0 \times 10^{-19} = -2.2 \times 10^{-21} \, \text{J} \, (\text{electron not ejected})KE=E−ϕ=3.978×10−19−4.0×10−19=−2.2×10−21J(electron not ejected)

Applications of Quantum Science

Solar Cells

Convert sunlight into electrical energy using the photoelectric effect.

Lasers

Quantum principles govern laser operation in medical and industrial applications.

Quantum Computing

Exploits wave-particle duality for advanced computational processes.

Common Mistakes in Quantum Science Problems

  1. Forgetting to convert energy units (e.g., eV to Joules).
  2. Misinterpreting negative kinetic energy values.
  3. Ignoring Planck’s constant in photon energy calculations.

Practice Questions

  1. Calculate the energy of a photon with a wavelength of 500 nm500 \, \text{nm}500nm.
  2. Explain how wave-particle duality applies to the double-slit experiment.
  3. Describe one real-world application of the photoelectric effect in solar technology.

 

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